Chemo??and regioselective allylic oxidation: Oxo??derivatives of 2??phospholene sugar analogs

VK Reddy, LN Rao, M Maeda, B Haritha…

Index: Reddy, Valluru Krishna; Rao, Lakonda Nagaprasada; Maeda, Motoki; Haritha, Buchammagari; Yamashita, Mitsuji Heteroatom Chemistry, 2003 , vol. 14, # 4 p. 320 - 325

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Citation Number: 20

Abstract

Abstract A convenient and facile chemo-and regioselective oxidation of the allylic methylene group in a 2-phospholene ring system afforded the novel carbonyl derivatives of 2- phospholenes (2a–i). The method gives high conversion and selectivity in the formation of allylic ketones. The advantages of this oxidation method in such a five-membered pseudo sugar 2-phospholene ring are mentioned, and the oxidation is examined on several ...