Tetrahedron Letters

Carboalumination/Ni-catalyzed couplings. A short synthesis of verticipyrone

BH Lipshutz, B Amorelli

Index: Lipshutz, Bruce H.; Amorelli, Benjamin Tetrahedron Letters, 2009 , vol. 50, # 18 p. 2144 - 2146

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Citation Number: 5

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Verticipyrone (1) has been synthesized in six overall steps from commercially available ethyl-2-methylacetoacetate. This represents the first successful application of a modified Negishi carboalumination-nickel-catalyzed cross-coupling reaction to a chloromethylated pyrone.

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