Epoxidation of alkenes bearing a carboxylic acid group by iron complexes of the tetradentate ligand N, N′-dimethyl-N, N′-bis (2-pyridylmethyl)-1, 2-diaminoethane …
LS Morris, MP Girouard, MH Everhart, WE McClain…
Index: Morris, Lilliana S.; Girouard, Michael P.; Everhart, Matthew H.; McClain, William E.; Van Paridon, John A.; Pike, Robert D.; Goh, Christopher Inorganica Chimica Acta, 2014 , vol. 413, p. 149 - 159
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Abstract
Abstract The addition of carboxylic acids enhances the rate and selectivity of alkene oxidations catalyzed by [(bpmen) Fe (OTf) 2](bpmen= N, N′-dimethyl-N, N′-bis (2- pyridylmethyl)-1, 2-diaminoethane). The syntheses and characterizations of four derivatives of this iron complex with varying substitutions on the pyridine ring and with a substituted piperazine backbone are reported. These [(L) Fe (OTf) 2] complexes and [(bpmen) Fe (OTf ...
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