DIMETHYLTRIFLUOROACETYLARSINE AND RELATED COMPOUNDS

WR Cullen, GE Styan

Index: Cullen,W.R.; Styan,G.E. Canadian Journal of Chemistry, 1966 , vol. 44, p. 1225 - 1227

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Citation Number: 5

Abstract

Altho~~gh fluoroacyl derivatives of transition metals have been l;no\\:n for seine time, little work has been done on the analogous derivatives of other metals and metalloids (1). Therefore, since compounds wit11 Si1-Sn and -4s-As bonds are readily cleaved by fluoroalkyl iodides to give fluoroalkyl derivatives of tin or arsenic (2-4), ... The last reaction inay proceed through initial formation of the trifluoroacetyl compound follo\\.ed by decarbonylation. (CI-I~)?.ASC(O)CI; ...