Reactions of difluorosilylene with halogen-substituted ethylenes. A reinvestigation of the reaction mechanism

TL Hwang, YM Pai, CS Liu

Index: Hwang, Tsai-lih; Pai, Yi-ming; Liu, Chao-shiuan Journal of the American Chemical Society, 1980 , vol. 102, # 25 p. 7519 - 7524

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Citation Number: 11

Abstract

Abstract: In supporting our recent discovery of the gas-phase reaction of monomeric difluorosilylene, reactions of SiFz with trans-and cis-difluoroethylene, vinyl chloride, and vinyl fluoride are studied in the gas phase. Compounds from insertion of monomeric SiF2 into carbon-halogen bonds are the only type of product obtained in these reactions. In order to avoid the complication that might be brought into the case of cocondensation ...