Synthesis of aryl-containing terpenoids based on 1, 4-dihydronaphthalene
…, RA Zainullin, AA Mukhamedzyanova, FZ Galin…
Index: Kukovinets; Kislitsyn; Zainullin; Mukhamedzyanova; Galin; Abdullin Russian Journal of Organic Chemistry, 2008 , vol. 44, # 3 p. 362 - 368
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Abstract
Abstract Successive transformations including oxidation of 1, 4-dihydronaphthalene into 1, 2, 3, 4-tetrahydronaphthalen-2-one, Reformatskii reaction of the latter with methyl bromoacetate, ozonolysis of the Reformatsky reaction product, and Emmons olefination of the aldehyde group in methyl 3-oxo-5-(2-formylphenyl) pentanate thus formed gave analogs of highly active dienoate juvenoids having an aromatic ring in their molecules.
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