Reactivity and mechanism of hydrolysis of phosphonamides
J Rahil, P Haake
Index: Rahil, Jubrail; Haake, Paul Journal of the American Chemical Society, 1981 , vol. 103, # 7 p. 1723 - 1734
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Citation Number: 64
Abstract
Abstract: The rates of hydrolysis of three phosphonamides, N, N- dimethylphenylphosphonamide (XII), N-(phenylphosphony1) pyrrolidine (XIII), and N- (phenylphosphony1) morpholine (XIV), have been investigated. There is first-order dependence on acidity in the pH range 4-7 with a pH independent region at low pHs, consistent with saturation due to complete formation of the neutral amide. The specific rate ...
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