… reactions of the SCl radical. Part1.—Rate constants and mechanisms of the reaction Cl+ C 2 H 4 S→ SCl+ C 2 H 4, SCl+ SCl→ products and SCl+ Cl 2→ SCl 2+ Cl

TP Murrells

Index: Murrells, Timothy P. Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1988 , vol. 84, p. 67 - 84

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Citation Number: 3

Abstract

The reaction of Cl atoms with ethylene sulphide, CHS, has been used as a source of SCl radicals in a discharge-flow system with detection of free-radical and molecular species by molecular-beam-sampling mass spectrometry. The rate constant for the overall reaction of Cl with CHS Cl+ CHS→ products (1) was found to