Journal of fluorine chemistry

Syntheses de cetones a chaine F-alkylee.

P Moreau, N Naji, A Commeyras

Index: Moreau,P.; Naji,N. Journal of Fluorine Chemistry, 1987 , vol. 34, p. 421

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Citation Number: 15

Abstract

Abstract Hemifluorinated ketones R CO RF, in which an F-alkyl chain (C 8 F 17 or C 6 F 13) is directly bound to the carbonyl group, were prepared from F-alkyl Grignard reagents. The reaction of acyl anhydrides (RCO) 2 O upon these organometallic derivatives constitutes a particularly competitive route to these ketones, compared to that of the corresponding acyl chlorides. The methyl (F-alkyl) ketones were also obtained by the ...