From stoichiometry to catalysis: electroreductive coupling of alkynes and carbon dioxide with nickel-bipyridine complexes. Magnesium ions as the key for catalysis
S Derien, E Dunach, J Perichon
Index: Derien, Sylvie; Dunach, Elisabet; Perichon, Jacques Journal of the American Chemical Society, 1991 , vol. 113, # 22 p. 8447 - 8454
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Citation Number: 110
Abstract
Conclusion In summary, on the basis of angle-resolved photoemission results and MNDO theoretical calculations, it appears that the initial adsorption of diethylcarborane on Si (1 1 1) at 90 K results in the loss of ethyl units. The adsorption of the parent nido-2, 3-C2B4H8 fragment is otherwise molecular. This molecular fragment bonds to the surface with the basal plane of the carborane molecule essentially parallel with the surface normal. ...
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