Hydroxylation by cytochrome P-450 and metalloporphyrin models. Evidence for allylic rearrangement
JT Groves, DV Adhyam
Index: Groves, John T.; Subramanian, Durga V. Journal of the American Chemical Society, 1984 , vol. 106, # 7 p. 2177 - 2181
Full Text: HTML
Citation Number: 239
Abstract
Abstract: The allylic hydroxylation of 3, 3, 6, 6-tetradeuteriocyclohexene, methylenecyclohexane, and@-pinene has been examined with phenobarbital-induced liver microsomal cytochrome P-450 (P-45OLM2) and with iron porphyrin and chromium porphyrin model systems. Aerobic and peroxide dependent enzymic regimes were investigated with purified P-45OLM2 and with microsomal suspensions. Epoixidation and allylic ...
Related Articles:
The Low Temperature Halogenation of Isobutylenes
[Arnold; Lee Journal of the American Chemical Society, 1953 , vol. 75, p. 5396,5399]
[Ardolino, Michael J.; Morken, James P. Journal of the American Chemical Society, 2014 , vol. 136, # 19 p. 7092 - 7100]
Reactions of Tosylhydrazide Derivatives Having Olefinic Groups
[Sato,T.; Homma,I. Bulletin of the Chemical Society of Japan, 1971 , vol. 44, p. 1885 - 1891]
Regiospecific addition of benzeneselenenyl halide to 1, 1-dis ubstituted olefins
[Ho, Pak-Tsun; Kolt, Ralph J. Canadian Journal of Chemistry, 1982 , vol. 60, p. 663 - 666]
The Effect of Ring Size on Diacyl Peroxide Decompositions1, 2
[Hart; Wyman Journal of the American Chemical Society, 1959 , vol. 81, p. 4891,4896]