Dienophilic thioaldehydes
E Vedejs, TH Eberlein, DL Varie
Index: Vedejs, E.; Eberlein, T. H.; Varie, D. L. Journal of the American Chemical Society, 1982 , vol. 104, # 5 p. 1445 - 1447
Full Text: HTML
Citation Number: 98
Abstract
In earlier work, we had found that transient S= CHCN (from Br2CHCN+ EtOCS; K+) could be trapped by 2-ethoxybutadiene to give the Diels-Alder adduct in 15% yield. Ic A report that a thioaldehyde generated by Norrish Cleavage of a phenacyl sulfide C6H5COCH2SCH2Y, 1 (Y= a penicillin-derived fragment) can be trapped in more respectable yield (55% thiirane using a diphenyldiazomethane trap) 4 encouraged us to reexamine the Diels-Alder ...
Related Articles:
On the Behavior of α, β-Unsaturated Thioaldehydes and Thioketones in the Diels-Alder Reaction
[Li, Guang Ming; Niu, Shuqiang; Segi, Masahito; Tanaka, Koichiro; Nakajima, Tadashi; Zingaro, Ralph A.; Reibenspies, Joseph H.; Hall, Michael B. Journal of Organic Chemistry, 2000 , vol. 65, # 20 p. 6601 - 6612]
An easy access to α, β-unsaturated thioacylsilanes: a useful route to silylated 1, 2-dithiins
[Capperucci, Antonella; Degl'Innocenti, Alessandro; Biondi, Simona; Nocentini, Tiziano; Rinaudo, Giuseppe Tetrahedron Letters, 2003 , vol. 44, # 14 p. 2831 - 2835]
[Block,E.; Iyer,R.; Grisoni,S. Journal of the American Chemical Society, 1988 , vol. 110, p. 7813]
[Block; Ahmad; Jain; et al. Journal of the American Chemical Society, 1984 , vol. 106, # 26 p. 8295 - 8296]
Formation of thiocarbonyl compounds in the reaction of ebselen oxide with thiols
[Glass, Richard S.; Farooqui, Firdous; Sabahi, Mahmood; Ehler, Kenneth W. Journal of Organic Chemistry, 1989 , vol. 54, # 5 p. 1092 - 1097]