Alkoxyamine C–ON Bond Homolysis: Stereoelectronic Effects

…, D Gigmes, SRA Marque, D Siri, P Tordo

Index: Beaudoin, Emmanuel; Bertin, Denis; Gigmes, Didier; Marque, Sylvain R. A.; Siri, Didier; Tordo, Paul European Journal of Organic Chemistry, 2006 , # 7 p. 1755 - 1768

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Citation Number: 36

Abstract

Abstract Alkoxyamines and persistent nitroxides are important regulators of nitroxide- mediated radical polymerization (NMP) reactions. Because polymerization times decrease with an increase in the rate constant for the homolysis of the C–ON bond between the polymer chain and the nitroxyl moiety, the factors influencing the cleavage rate constant are of considerable interest. Therefore, it was interesting to check whether the methyl effect (+ ...