Synthesis and heterocyclization of dithiocarbamoylacetoacetic esters and anilides

…, EA Ghazaryan, AP Engoyan, RT Grigoryan…

Index: Dovlatyan; Eliazyan; Pivazyan; Ghazaryan; Engoyan; Grigoryan; Mirzoyan Chemistry of Heterocyclic Compounds, 2000 , vol. 36, # 5 p. 593 - 597

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Citation Number: 5

Abstract

The action o[" salt.; of N-monosubstituted dithiocarbamic acids on ct-chloroacetoaeetic ester and the corresponding anilide led to the isolation o[" the ct-dithiocarbamoyl derivatives. These derivatives are converted, on standing or heating, to the ethyl ester and anilide q['4-methyl-3- methyl(ao,l)-2-thiooxy-l,3- thiazolyl-5-carboxylic acids, which can be converted to the corresponding acid, acid chloride, and anilide. ... Keywords: dithiocarbamates, thiourea, thiazolines, c~- ...