Inorganic Chemistry

Preparation and characterization of salts containing cations of tricoordinate boron

CK Narula, H Noeth

Index: Narula, Chaitanya K.; Noeth, Heinrich Inorganic Chemistry, 1984 , vol. 23, p. 4147 - 4152

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Citation Number: 19

Abstract

1, 3-Dimethyl-2-triflato-1, 3, 2-diazaborolidine (3) reacts with various amines in a 1: 1 ratio with displacement of the triflato group and formation of triflate salts containing cations with tricoordinate boron. cup'-Bipyridyl in a 1: l molar ratio gives a salt containing a tetracoordinated boron atom. N, N, N', N'-Tetramethylethylenediamine on the other hand produces a 1: l adduct, which in CH2CI2 solution provides evidence for an equilibrium ...