Total synthesis of peroxyacarnoates A and D: metal-mediated couplings as a convergent approach to polyunsaturated peroxides
C Xu, JM Raible, PH Dussault
Index: Xu, Chunping; Raible, Joseph M.; Dussault, Patrick H. Organic Letters, 2005 , vol. 7, # 12 p. 2509 - 2511
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Citation Number: 24
Abstract
The first syntheses of peroxyacarnoates A and D, members of a family of enyne-containing alkoxydioxanes, have been achieved on the basis of chemoselective ozonolysis within a polyunsaturated framework and Pd-mediated cross-couplings of a functionalized 1, 2- dioxane.
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