One-pot synthesis of N-[(trimethylsilyl) methyl] imines and (trimethylsilyl) methyl-substituted heterocumulenes from (trimethylsilyl) methyl azide

O Tsuge, S Kanemasa, K Matsuda

Index: Tsuge, Otohiko; Kanemasa, Shuji; Matsuda, Koyo Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2688 - 2691

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Citation Number: 56

Abstract

N-((Trimethykily1) methyl) imines and heterocumulenes bearing a (trimethylsily1) methyl group adjacent to the cumulene moiety (abbreviated as TMSM-heterocumulenes) are useful reagenb in the field of heterocyclic synthesis. The only derivative of N-((trimethylsily1)- methy1) imine reported to date, N-benzylidene (tri-methylsilyl) methylamine,'has been found to be a useful precursor for the nonstabilized azomethine ylide 1, 3-dipole2 and the ...