Striking AcOH acceleration in direct intramolecular allylic amination reactions

F Nahra, F Liron, G Prestat, C Mealli…

Index: Nahra, Fady; Liron, Frederic; Prestat, Guillaume; Mealli, Carlo; Messaoudi, Abdelatif; Poli, Giovanni Chemistry - A European Journal, 2009 , vol. 15, # 42 p. 11078 - 11082

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Citation Number: 74

Abstract

Direct functionalisation of hydrocarbons has attracted much interest for its great potential in organic synthesis.[1] These processes, by avoiding the introduction of functional groups, have atom-and step-economical advantages. In this context, allylic functionalisation of olefins [2] is an active research domain, as witnessed by recent papers on Rh-,[3] Pd-[4] and Ru-catalysed [5] allylic acyloxylations and aminations of olefins.

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