Über die Synthese von substituierten 2-Aminopyrrolinen, 2. Mitt.
W Klötzer
Index: Kloetzer,W. Monatshefte fuer Chemie, 1970 , vol. 101, p. 1841 - 1850
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Citation Number: 4
Abstract
Abstract Geminal dimethyl substituted N-acylaziridines react with diphenylacetonitrite (as anion), the course of the reaction depending on the nature of the acyl group. N-carbethoxy- 2.2-dimethylaziridine undergoes abnormal aziridine ring opening at the gem.-substituted C atom and migration of the carbethoxy group accompanied by 5-membered ring closure to yield as major product N-2-carbethoxylamino-3.3-diphenyl-4.4-dimethylpyrroline-1 (1). In ...
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