The Journal of Organic Chemistry

Aerosol direct fluorination: syntheses of the highly branched ketones, F-pinacolone and" F-provalone"

JL Adcock, ML Robin

Index: Adcock, James L.; Robin, Mark L. Journal of Organic Chemistry, 1984 , vol. 49, # 8 p. 1442 - 1445

Full Text: HTML

Citation Number: 11

Abstract

In general, routes to perfluoro ketones, other than the aerosol direct fluorination process, require either the prior preparation of highly chlorinated species or (in most cases) highly fluorinated species. The Swarts reaction and other reactions involving halogen exchange require preparation of the corresponding chloro carbons prior to fluorination, and the higher perchloro carbons are often difficult to prepare. mical preparations of perfluoro ketones ...