Pyridinium salts structurally related to NAD (P)+ as enolate transferring agents

SH Mashraqui, RM Kellogg

Index: Mashraqui, Sabir H.; Kellogg, Richard M. Journal of the American Chemical Society, 1983 , vol. 105, # 26 p. 7792 - 7793

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Citation Number: 16

Abstract

The NAD(P)+/NAD(P)H redox couple is known for the transfer of "hydride" equivalents. However, other anionic species, for example, CN, SR, and enolate, have been reported to add to pyridinium salts structurally related to NAD(P)+.I For the case of thiolate, transfer in a manner resembling that involved for "hydride" has been shown.2 We find that enolates can also be transferred by analogues of the NAD(P)+/NAD(P)H system thereby allowing the realization of aldol ...