Dalton transactions

Nickel and iron complexes with N, P, N-type ligands: synthesis, structure and catalytic oligomerization of ethylene

A Kermagoret, F Tomicki, P Braunstein

Index: Kermagoret, Anthony; Tomicki, Falk; Braunstein, Pierre Dalton Transactions, 2008 , # 22 p. 2945 - 2955

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Citation Number: 33

Abstract

The N, P, N-type ligands bis (2-picolyl) phenylphosphine (1), bis (4, 5-dihydro-2- oxazolylmethyl) phenylphosphine (2), bis (4, 4-dimethyl-2-oxazolylmethyl) phenylphosphine (3) and bis (2-picolyloxy) phenylphosphine (4) were used to synthesize the corresponding pentacoordinated Ni (II) complexes [Ni {bis (2-picolyl) phenylphosphine} Cl2](6),[Ni {bis (4, 5- dihydro-2-oxazolylmethyl) phenylphosphine} Cl2](7),[Ni {bis (4, 4-dimethyl-2- ...