The Journal of Organic Chemistry

Additions of allylic Grignard reagents to o-allylphenol

HG Richey Jr, MS Domalski

Index: Richey, Herman G.; Domalski, Martin S. Journal of Organic Chemistry, 1981 , vol. 46, # 19 p. 3780 - 3783

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Citation Number: 6

Abstract

Addition of an excess of an organoniagnesiurn compound, particularly if allylic, to the niultiple bond of an alkenol, alkynol, or allenol is often assisted hy the meta-lated hydroxyl group.'Metalated amino groups also assist addition, but some comparisons suggest that their assistance is less effective than that afforded by metalated hydroxyl groups. 2 Moreover, one comparison suggests that a phenylaminu group is more effective than a ...