Nickel??Catalyzed Electrochemical Arylation of Activated Olefins

…, D Dupré, G Falgayrac, JY Nédélec

Index: Condon, Sylvie; Dupre, Daniel; Falgayrac, Gilles; Nedelec, Jean-Yves European Journal of Organic Chemistry, 2002 , # 1 p. 105 - 111

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Citation Number: 17

Abstract

Abstract Nickel-catalyzed electrochemical conjugate additions of substituted aryl bromides to activated olefins under recently optimized reaction conditions are reported. Good to high yields were obtained, whatever the nature of substituents in the meta-and para-positions of the benzene ring. In the ortho-substituted series, yields were good with electron-donating substituents, but low with electron-withdrawing groups. The activation of aryl chlorides and ...