The Journal of Organic Chemistry

Reduction of thiol esters by lithium aluninum hydride-aluminum chloride

DE Bublitz

Index: Bublitz,D.E. Journal of Organic Chemistry, 1967 , vol. 32, p. 1630 - 1631

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Citation Number: 13

Abstract

N-Lithiodimethyl Sulfone Imine.-Dimethyl sulfone imine (mp 56-58') was prepared as described by Bentley, McDermott, and Whitehead. 10 To a solution of 514 mg (5.52 mmoles) of the sulfone imine in 5 ml of benzene under argon at room temperature was added 4.08 ml (5.52 mmoles) of 1.35 N n-BuLi. The resulting, milky white liquid was then stirred for 2 hr and evaporated to dryness in oacuo (0.5 mm). The infrared spectrum of the resulting, white ...