Organometallics

Strikingly Different Reactivity Patterns of Fischer Alkoxycarbene and Thiocarbene Complexes in Experimental and Theoretical Studies

B Karatas, I Hyla-Kryspin, R Aumann

Index: Aumann, Rudolf; Schroeder, Jochen Chemische Berichte, 1990 , vol. 123, # 10 p. 2053 - 2058

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Citation Number: 7

Abstract

Striking differences in the reactions of alkoxycarbene and thiocarbene complexes of M = Cr, W are reported and explained on the basis of DFT/BP86 calculations. ... Striking differences in the reactions of alkoxycarbene and thiocarbene complexes of chromium and tungsten are