Resolution and absolute configuration of K-region trans dihydrodiols from polycyclic aromatic hydrocarbons

…, PJ Van Bladeren, N Shirai, DM Jerina

Index: Balani, S. K.; Bladeren, P. J. van; Shirai, N.; Jerina, D. M. Journal of Organic Chemistry, 1986 , vol. 51, # 10 p. 1773 - 1778

Full Text: HTML

Citation Number: 29

Abstract

K-region trans dihydrodiols of benzo [c] phenanthrene, chrysene, pyrene, and dibenz [c, h] acridine have been resolved as their diastereomeric diesters with (-)-(menthy1oxy) acetic acid, and their absolute configurations have been assigned by the application of circular dichroism and exciton chirality methods. For these as well as the K-region trans dihydrodiol derivatives from five other hydrocarbons, a consistent pattern of physical properties has ...

Related Articles:

Solvolysis of K-region arene oxides: substituent effects on reactions of benz [a] anthracene 5, 6-oxide

[Nashed, Nashaat T.; Balani, Suresh K.; Loncharich, Richard J.; Sayer, Jane M.; Shipley, David Y.; Mohan, Ram S.; Whalen, Dale L.; Jerina, Donald M. Journal of the American Chemical Society, 1991 , vol. 113, # 10 p. 3910 - 3919]

… hydrocarbon-DNA interactions: a comparison of DNA influences on the reactivities of (.+-.)-trans-7, 8-dihydroxy-anti-9, 10-epoxy-7, 8, 9, 10-tetrahydrobenzo [a] pyrene …

[Urano, Shigeyuki; Price, Harry L.; Fetzer, Sharon M.; Briedis, Anita V.; Milliman, Ann; LeBreton, Pierre R. Journal of the American Chemical Society, 1991 , vol. 113, # 10 p. 3881 - 3893]

More Articles...