Cyclic peroxides. 67. Synthesis and characterization of 7-spirocyclopropyl-2, 3-dioxabicyclo [2.2. 1] hept-5-ene
W Adam, I Erden
Index: Adam,W.; Erden,I. Journal of Organic Chemistry, 1978 , vol. 43, # 13 p. 2737 - 2738
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Citation Number: 14
Abstract
Summary: The title compound, 3, was prepared by diimide reduction of the unstable endoperoxide 2 which was obtained by photooxygenation of spiro [2.4] hepta-4, 6-diene (1) and characterized by catalytic reduction to its diol 4 and basecatalyzed rearrangement to its ketol 5.
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