Chemische Berichte

Synthese und Reaktionen eines sterisch gehinderten Olefins, trans??2, 2, 3, 4, 5, 5??Hexamethyl??3??hexen

D Lenoir

Index: Lenoir,D. Chemische Berichte, 1978 , vol. 111, p. 411 - 414

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Citation Number: 22

Abstract

Scope and limitation of the Ti"-induced coupling reaction for the sterically congested carbonyl compounds tert-butyl methyl ketone (4), tert-butyl ethyl ketone, and pivalaldehyde are discussed. The new olefin 5 has been prepared; the unusual chemical and physical behavior has been described by its inherent steric strain.