Efficient methods for oxidation of alcohols.

K Narasaka, A Morikawa, K Saigo…

Index: Narasaka,K. et al. Bulletin of the Chemical Society of Japan, 1977 , vol. 50, p. 2773 - 2776

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Citation Number: 86

Abstract

Treatment of alkoxymagnesium bromides, prepared in situ from alcohols and Grignard reagent, with N-chlorosuccinimide, m-chloroperbenzoic acid, or (diacetoxyiodo) benzene in the presence of t-butoxymagnesium bromide afforded the corresponding carbonyl compounds in good yields. A wide variety of alcohols, after being converted into their bromomagnesium salts by treatment with propylmagnesium bromide, were also ...