Reactions of Bromomagnesium Enolates of Mesityl Ketones. II. Condensation

RC Fuson, WO Fugate, CH Fisher

Index: Fuson; Fugate; Fisher Journal of the American Chemical Society, 1939 , vol. 61, p. 2362,2363

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Citation Number: 8

Abstract

A study of its reactions has revealed the somewhat surprising fact that in all cases it behaves as though it were a true Grignard reagent. This is perhaps most striking in connection with condensation with carbonyl compounds. In the work presently reported condensation has been effected with acid chlorides, esters, carbon dioxide, aldehydes and ketones. The product in each instance is that which is predicated by formula 11. Acid chlorides and ...