One-step synthesis of hyperbranched dendritic polyesters

CJ Hawker, R Lee, JMJ Fréchet

Index: Hawker; Lee; Frechet Journal of the American Chemical Society, 1991 , vol. 113, # 12 p. 4583 - 4588

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Citation Number: 1031

Abstract

Abstract: The one-step synthesis of a hyperbranched polyester possessing a dendritic structure has been achieved by thermal self-condensation of 3, 5-bis (trimethylsiloxy) benzoyl chloride. The hyperbranched polyesters are obtained in yields of 80% or greater and with polystyrene equivalent weight average molecular weights in the range 30000 to almost 200000. The polydispersity and the molecular weights of the polyesters were found ...