Synthesis of a new class of unsymmetrical PCP′ pincer ligands and their palladium (II) complexes: X-ray structure determination of PdCl {C 6 H 3-2-CH 2 PPh 2-6- …

…, D Morales-Morales, S Hernández-Ortega…

Index: Naghipour, Ali; Sabounchei, Seyyed Javad; Morales-Morales, David; Hernandez-Ortega, Simon; Jensen, Craig M. Journal of Organometallic Chemistry, 2004 , vol. 689, # 15 p. 2494 - 2502

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Citation Number: 43

Abstract

The unsymmetrical PCP′ pincer ligands {C6H4-1-CH2PPh2-3-CH2PBut2} and {C6H4-1- CH2PPh2-3-CH2PPri2} and the corresponding palladium complexes: PdCl {C6H3-2- CH2PPh2-6-CH2PBut2} and PdCl {C6H3-2-CH2PPh2-6-CH2PPri2} have been synthesized in good yields. The molecular structure of PdCl {C6H3-2-CH2PPh2-6-CH2PBut2} was determined through a single crystal X-ray diffraction study. The palladium center was ...

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