Synthesis of 1, 2, 3, 4-tetrahydrocarbazoles and related tricyclic indoles
TL Scott, N Burke, G Carrero-Martínez, BCG Söderberg
Index: Scott, Tricia L.; Burke, Nicholas; Carrero-Martinez, Grissell; Soederberg, Bjoern C.G. Tetrahedron, 2007 , vol. 63, # 5 p. 1183 - 1190
Full Text: HTML
Citation Number: 12
Abstract
Reduction of 2-(2-nitrophenyl)-2-cyclohexene-1-ones using palladium on carbon under 1atm of hydrogen gas at ambient temperature affords 1, 2, 3, 4-tetrahydrocarbazoles in excellent isolated yields. The starting materials were prepared by intermolecular Stille coupling of 2-iodo-2-cyclohexen-1-ones with 2-(tributylstannyl)-1-nitrobenzenes.
Related Articles:
[Youn, So Won; Pastine, Stefan J.; Sames, Dalibor Organic Letters, 2004 , vol. 6, # 4 p. 581 - 584]
[Youn, So Won; Pastine, Stefan J.; Sames, Dalibor Organic Letters, 2004 , vol. 6, # 4 p. 581 - 584]
Highly regioselective functionalization of 2, 3-dialkyl substituents on indoles
[Naruse, Yuji; Ito, Yoshitaka; Inagaki, Satoshi Journal of Organic Chemistry, 1991 , vol. 56, # 6 p. 2256 - 2258]