The Journal of Organic Chemistry

Synthesis and 19F and 13C NMR Studies of a Series of 4-Substituted Fluorocubanes: Resonance Dependence of 19F Chemical Shifts in a Saturated System

EW Della, NJ Head

Index: Della, Ernest W.; Head, Nicholas J. Journal of Organic Chemistry, 1995 , vol. 60, # 16 p. 5303 - 5313

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Citation Number: 25

Abstract

Considerable interest has recently been directed to developing an understanding of the transmission modes of substituent electronic and electrostatic effects in fully saturated systems. The use of 19F NMR spectroscopy for studying the ground state has proven to be very re~ arding, l-~ although the results obtained employing the 19F probe are frequently found to be different than those arising from reactivity~ tudies.~ The effect of substituents ...