1, 3-Addition-Type Ring-Opening Polymerization of Cyclic Phosphonites

T Mukaiyama, T Fujisawa, Y Tamura…

Index: Mukaiyama,T. et al. Journal of Organic Chemistry, 1964 , vol. 29, p. 2572 - 2575

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Citation Number: 36

Abstract

Ethylene and trimethylene phenylphosphonites were prepared from phenylphosphonous dichloride and corresponding glycols. Ethylene n-propylphosphonite was obtained by reacting ethylene phosphorochloridite with n-propylrnagnesium bromide. The phosphonites, being reacted with such acids as hydrogen chloride and carboxylic acids, have given ring- opening addition compounds, which suggests the possibility that these phosphonites may ...