Fast cleavage reactions following electron transfer. Reduction of 1, 1-dinitrocyclohexane
…, DH Evans, P Hapiot, P Neta
Index: Ruehl, Janet C.; Evans, Dennis H.; Hapiot, Philippe; Neta, Pedatsur Journal of the American Chemical Society, 1991 , vol. 113, # 14 p. 5188 - 5194
Full Text: HTML
Citation Number: 29
Abstract
Abstract: One-electron reduction of 1, l-dinitrocyclohexane is followed by rapid cleavage of a CN bond, giving nitrite and 1-nitrocyclohexyl radical. The rate constant has been determined in dimethylformamide by homogeneous redox catalysis (1.6 X lo6 sI) and in aqueous solution by pulse radiolysis (1.1 X IO6 sl). These values are of the order of IO6 larger than the rate constant for cleavage of mononitroalkane radical anions. In the case of ...
Related Articles:
Copper-Catalyzed Homodimerization of Nitronates and Enolates under an Oxygen Atmosphere
[Do, Hien-Quang; Tran-Vu, Hung; Daugulis, Olafs Organometallics, 2012 , vol. 31, # 22 p. 7816 - 7818]
Rohstoffe und Zwischenprodukte
[Grundmann; Haldenwanger Angewandte Chemie, 1950 , vol. 62, p. 556]
[Bordwell, Frederick G.; Clemens, Anthony H. Journal of Organic Chemistry, 1982 , vol. 47, # 13 p. 2510 - 2516]
[Bordwell, Frederick G.; Clemens, Anthony H. Journal of Organic Chemistry, 1982 , vol. 47, # 13 p. 2510 - 2516]
[Bordwell, Frederick G.; Bausch, Mark J.; Wilson, Craig A. Journal of the American Chemical Society, 1987 , vol. 109, # 18 p. 5465 - 5470]