Stereochemical studies of dioxetane formation with hindered olefins

Y Kabe, T Takata, K Ueno, W Ando

Index: Kabe,Y.; Takata,T.; Ueno,K. Journal of the American Chemical Society, 1984 , vol. 106, p. 8174

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Citation Number: 38

Abstract

Abstract: Two stereoisomeric di-tert-butylbis (bicyclo [3.3. l] non-9-ylidenes)(anti-2 and syn- 2) and related hindered olefins were synthesized, and their reactivities and stereochemistries in various dioxetane formations were evaluated. Whereas the singlet oxygenation of a series of three closely related olefins, 1, 3, and 4, gave the corresponding dioxetanes in almost the same reactivity, in the electrode-catalyzed oxygenation the ...