Electrochemical carboxylation coupled with nitrite reduction catalyzed by [Fe4S4 (SPh) 4] 2-and [Mo2Fe6S8 (SPh) 9] 3

K Tanaka, R Wakita, T Tanaka

Index: Tanaka, Koji; Wakita, Ryuhei; Tanaka, Toshio Journal of the American Chemical Society, 1989 , vol. 111, # 7 p. 2428 - 2433

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Citation Number: 21

Abstract

Abstract: The controlled-potential electrolysis of C02-saturated CH3CN containing [Fe4S,(SPh), l2-, NOT, PhCOCH3, and a dehydration agent at-1.25 V vs SCE catalytically produced not only N2 accompanied by a small amount of N20 but also PhCOCH2COO-with the mole ratio 1: 7. N20;-as a precursor of N20 was confirmed in the reaction mixture. The reduction of NO; catalyzed by the reduced species of [Fe4S4 (SPh), l2-, therefore, ...