A highly stereoselective olefination of aldehydes using new zinc and zirconium 1, 1-bimetallic reagents
CE Tucker, P Knochel
Index: Tucker, Charles E.; Knochel, Paul Journal of the American Chemical Society, 1991 , vol. 113, # 26 p. 9888 - 9890
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Citation Number: 50
Abstract
Sa nium 1, l-bimetallic reagents. In the course of our continuing studies on the reactivity of 1, l-bimetalloalkanes of zinc and magnesium, 2 we needed a more general preparation of these reagents3 allowing the access to a variety of carbon skeletons. Our attention was drawn to the pioneering work of J. S~ hwartz,'j-~~~ who demonstrated that various alkenyl organometallics can be hydrometallated leading to several new classes of 1, l-bimetallic ...
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