Homogeneous catalysis: IX. Hydrosilylation using tris (Pentanedionato) rhodium (III)-trialkylaluminium as catalyst
AJ Cornish, MF Läppert
Index: Cornish, Andrew J.; Lappert, Michael F. Journal of Organometallic Chemistry, 1984 , vol. 271, # 1-3 p. 153 - 168
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Citation Number: 28
Abstract
Abstract The two component (Ziegler) catalyst [Rh (acac) 3]-AlEt 3 (or an analogue with an alternative cocatalyst) has been investigated for the hydrosilylation by SiHX 3 of alkynes, dienes, alkenes, styrene, or allylbenzene at 60 C. Terminal alkynes did not yield adducts, but internal alkynes RC CR′ gave products of cis-addition with SiHEt 3 or SiHEt 2 Me (but not SiH (OEt) 3), without regiospecificity for the case of R≠ R′. Acyclic dienes gave 1/1 ...
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