Bulletin of the Chemical Society of Japan

The reaction of bis (dimethylglyoximato)(pyridine) cobalt (I), cobaloxime (I), with 2-(allyloxy) ethyl halides and the photolysis of the resulting organo-cobaloximes.

M Okabe, M Tada

Index: Okabe, Masami; Tada, Masaru Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 5 p. 1498 - 1503

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Citation Number: 41

Abstract

The reactions of 2-(allyloxy) ethyl halides with cobaloxime (I) gave (tetrahydro-3-furanyl) methylcobaloximes via an electron transfer from cobaloxime (I) to the halides to give radical anions. The rupture of a halide ion to give an organic radical and the ring closure to give a (tetrahydro-3-furanyl) methyl radical are followed by the radical coupling between the organic radical and the cobaloxime (II). The structures of the organo-cobaloximes were ...