Hydrogen Transfer. III. 1 Reaction of p-Ethyltoluene and p-Propyltoluene with Methylcyclohexene. Synthesis of Diarylalkanes

H Pines, DR Strehlau, VN Ipatieff

Index: Pines; Strehlau; Ipatieff Journal of the American Chemical Society, 1949 , vol. 71, p. 3534,3538

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Citation Number: 12

Abstract

Summary The action of Acetobacter suboxydans upon volemitol proceeds readily and nearly quantitatively to produce both D-mannoheptulose and D-altroheptulose (= sedoheptulose). This result is in agreement with the specificity rule of Hann, Tilden and Hudson for the action of A. suboxydans. The action of Acetobacter xylinurn upon volemito1 is slow and incomplete; only one end of the molecule appears to be oxidized, and the sirupy ketose, which was ...

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