The Journal of Organic Chemistry

Variable electronic properties of the CSNMe2 thioamide group

X Creary, T Aldridge

Index: Creary, Xavier; Aldridge, Timothy Journal of Organic Chemistry, 1991 , vol. 56, # 13 p. 4280 - 4285

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Citation Number: 22

Abstract

Rates of solvolysis of the substituted cumyl chlorides were determined in ethanol and these rate data (Table I) were used to determine u+ values. The CONMe2 group slows the solvolysis rate in both the mete and para positions. The m-CSNMe2 group is also rate retarding, but