Tetrahedron letters

Palladium-catalyzed acylation of activated alkenes with bridgehead acid chlorides

K Hori, M Ando, N Takaishi, Y Inamoto

Index: Hori, Kimihiko; Ando, Masatomo; Takaishi, Naotake; Inamoto, Yoshiaki Tetrahedron Letters, 1987 , vol. 28, # 47 p. 5883 - 5886

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Citation Number: 16

Abstract

Abstract Bridgehead acid chlorides 1a and 1b react with activated alkenes 2 in the presence of a catalytic amount of palladium and 1 equiv of a tertiary amine. The reaction proceeds regio-and stereoselectively at the terminal carbon atoms to yield acylated alkenes 3 with E- configuration.