Journal of heterocyclic chemistry

Synthesis and thermal rearrangement of allylic 3, 5, 6??trimethyl??2??pyrazinylacetates: A heterocyclic carroll rearrangement

KF Podraza

Index: Podraza, Kenneth F. Journal of Heterocyclic Chemistry, 1986 , vol. 23, p. 581 - 583

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Citation Number: 1

Abstract

Abstract The synthesis of allylic 3, 5, 6-trimethyl-2-pyrazinylacetates 2–4 has been achieved by the reaction of 3, 5, 6-trimethyl-2-pyrazinylacetic acid lithium salt (1) with phenyl dichlorophosphate followed by addition of the allylic alcohol. On thermolysis, the allylic β-