Total syntheses of bacillamide C and neobacillamide A; revision of their absolute configurations
V Martínez, D Davyt
Index: Martinez, Veronica; Davyt, Danilo Tetrahedron Asymmetry, 2013 , vol. 24, # 24 p. 1572 - 1575
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Citation Number: 3
Abstract
Several natural products containing 2-(1-aminoethyl)thiazole-4-carboxylic acid 1 have been isolated from microorganisms that grow in marine and terrestrial biomass (Fig. 1). This scaffold has an asymmetric carbon atom on the α-aminoethyl group that biosynthetically derives from alanine. The (S)-enantiomer of 1 is derived from l-(+)-alanine and the (R)-enantiomer from d-(−)-alanine. Despite the importance of the enantiomeric forms of bioactive natural ...
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