Tetrahedron

Alkylation of dianions derived from 2-(1-iminoalkyl) phenols: synthesis of functionalized 2-acyl phenols

C Cimarelli, G Palmieri

Index: Cimarelli, Cristina; Palmieri, Gianni Tetrahedron, 1998 , vol. 54, # 51 p. 15711 - 15720

Full Text: HTML

Citation Number: 33

Abstract

A method has been developed for the almost exclusive C-alkylation of the 2-(1-iminoalkyl) phenols1, important organic compounds with a range of employment, which allows the preparation of complex derivatives4 with good yields starting from easily available materials. The operational simplicity of this method take advantages in providing a variety of alkylated 2-acyl phenols5 by an easy hydrolysis of the 2-(1-iminoalkyl) phenols4.

Related Articles:

Regioselective reductive openings of acetals; mechanistic details and synthesis of fluorescently labeled compounds

[Johnsson, Richard; Mani, Katrin; Cheng, Fang; Ellervik, Ulf Journal of Organic Chemistry, 2006 , vol. 71, # 9 p. 3444 - 3451]

Intramolecular proton transfer in photohydration reactions

[Kalanderopoulos, Peter; Yates, Keith Journal of the American Chemical Society, 1986 , vol. 108, # 20 p. 6290 - 6295]

More Articles...