Tetrahedron

Electronic spectra of organic molecules and their interpretation—IX: Side chain and terminal group effects on the K and B bands of anisole derivatives

JE Bloor, A Burawoy

Index: Bloor,J.E.; Buraway,A. Tetrahedron, 1964 , vol. 20, p. 861 - 869

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Citation Number: 7

Abstract

The effect of substituents X OH, NH2, NH3+, Ph, C N, Cl, Br, and I in the o-, m-and p- isomers of MeOC6H4CH2X on the K and B bands have been measured and interpreted qualitatively in terms of the hypotheses of terminal and side chain group effects. For the K bands the electron migration accompanying light absorption is along the long axis of molecule so that substituents orientated para to each other are terminal groups and can ...