The Journal of Organic Chemistry

Multiple Substituent Effects in the Solvolysis and Thiosulfate Reactions of 4-Substituted α-Chloro-3-nitrotoluenes

R Fuchs, DM Carlton

Index: Fuchs,R.; Carlton,D.M. Journal of Organic Chemistry, 1962 , vol. 27, p. 1520 - 1523

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Citation Number: 18

Abstract

MAY, 1962 4-SUBSTITUTED a-CHLORO-3-BITIZOTOLUENES 1521 some years that the two branches of the Hammett plot do not result from grossly different mechanisms; in a number of cases second-order kinetics have been established throughout a series. In general the unsubstituted benzyl compound shows the minimum rate4 in the p-substituted series, although a variety of nucleophiles, lS2 solvents, 2 and ionic strength^,^ have been ...